| 教學內容 |
1.原子構造:週期表,de Broglie 方程式,氫原子光譜與波耳氫原子理論,Rydberg 方程式,多電子原子光譜,Aufbau構築原理,Pauli不共容原理,Hund通則,Heisenberg不確定原理,Schrodinger方程式,量子數,原子軌道,電子組態,游離能,電子親合力.
2.化學鍵結理論:Lewis構造式,價鍵理論,VSEPR理論,分子軌道理論.
3.群論:對稱元素與對稱操作,矩陣,對稱乘法表,特徵表,可化簡與不可化簡表示式,在分子紅外光譜之應用,
4.酸鹼理論:酸鹼定義(Arrehnius,Bronsted-Lowry,Lewis,Solvent System),酸性強度,電子因素與立體因素,HSAB原理.
5.晶體構造:單位晶胞,原子堆疊方式,立方體,體心立方,面心立方,六方最密堆積,Bragg方程式,離子晶體構造. |
Syllabus |
1.Atomic Structure:Periodic Table,de Broglie equation,Hydrogen atom spectrum, Bohr Theory,
Rydberg equation,Many-electron atom spectrum,
Aufbau process,Pauli exclusion principle,Hund's rule, Heisenberg uncertainty principle, Schrodinger equation, Quantum numbers, Electron configuration, Ionization potential, Electron
affinity.
2.Chemical Bonding Theory: Lewis Structures, Valence Bond Theory, VSEPR Theory, Molecular Orbital Theory.
3.Group Theory:Symmetry Elements and Symmetric Operations,Multiplication Table,Character Table,
Reducible and Irreducible Representations, Application to Molecular IR Spectra.
4.Acids and Bases:Definitions(Arrehnius,Bronsted-Lowry,Lewis,Solvent System), Acidic Strength, Electronic Factor,Steric Factor,HSAB Principle.
5.Crystal Structures:Unit Cell, Atomic Packing,
Cubic Structure, BCC, FCC, HCP, Bragg's
Equation,Ionic Crystal Structures. |